Maybe. But his knowledge of the jutsu wasn't as extensive as Kabuto or Oro's.... Im not sure if he has the ability to break it, even if he was the one who invented it. If he does, I think he'd only be able to free himself, and not the other 3 hokages. Im not sure, I'll need to re-read the chapter where Madara broke free.
I don't see things going well for sasuke, and that's fine with me. He's such a fuckin emo.