.
But, to be on-topic a bit, Brake fluid/Auto-trans fluid would probably do the trick nicely.
Brake fluid is highly flammable. It burns very much like motor oil. We used to fill a can with chlorine tablets (used to treat pool water), then pour brake fluid into the can until full. After a minute or three, it would auto-ignite and create a column of impressive flame a good few meters high. Nice improvised 4th of July display.

Trans fluid I can't speak to direct experience, but it is a petroleum oil, so I suspect that it will ignite at some temperature or another. Suggest google and wikipedia as a first-stop check on that ... include "MSDS" or "Materials Safety Data Sheet" in google search string and you will get the exact ignition temperature. Might be safe enough at lower temps and if isolated from oxygen.
There are specialized silicon oils. I used to use a vacuum bell jar that used heated oil to pull a hard-space level vacuum. Can't remember the details on it anymore; too many years ago. But, I
think it ran about 200 degrees C for normal operating temps. Can't remember the proper name for the type of pump it's called (condenser oil pump?) ... but the oil in it handles high temp without cracking or igniting. It's
probably an acceptable material for this type of application. I'd definitely want to look up its heat capacity to guess at its efficiency; there's actually almost nothing that can beat good ol' H
2O for heat capacity, though.