As far as I can tell, both the TG585 and the DC-202 are routers, not switches. This means that they can allow several devices to connect to the internet, but they cannot allow those devices to connect to each other. This is different to a switch, which allows all connected devices to connect to each other, not just to the internet.
The only way to allow all your devices to connect to each other is to buy an ethernet switch, and connect your devices to that. So it will look like this:
internet > Thomson Gateway (TG585 v7) > Ethernet Switch >1 PC and Wireless connections.
> Sitecom (DC-202v6) > PC
> NAS
Basically, anything connected to the ethernet switch will be able to talk to anything else connected to the switch - but not to anything connected to the TG585. I'm not sure if you'll be able to get away with having multiple devices connected to the Sitecom or not, if it's behind the switch, so you'll have to experiment with that. I have a similar setup at home myself, with fewer devices, and it works well.
EDIT: Something like
this will work very well for the switch. You can probably get a similar one with fewer ports for cheaper if you look around a bit, but I'd try and avoid the really cheap ones, since they tend to be less reliable.